Macromolecular Symposia

Karla Calfumán, Paulina Dreyse, Camilo García, Maria J. Aguirre, Tomás Beltrán, Eva Guillamón, Iván Sorribes, Cristian Vicent, Rosa Llusar, Mauricio Isaacs

Research output: Contribution to conferencePaper

9 Citations (Scopus)

Abstract

This paper describes the electrochemical reduction of nitrite ion in 0.1 M NaClO4, on glassy carbon or ITO electrodes modified with mixtures PVC- tetraruthenated metalloporphyrins. This electrode is able to keep the extraordinary electrocatalytic properties of the macrocycle allowing multielectronic transfers and a great stability as a consequence of the inclusion of the macrocycles into a polymeric support such as PVC. On the other hand, the electrochemical reduction of nitrite ion on these modified electrodes studied by cyclic voltammetry shows an enhancement in the current values and lower overpotential compared with the activity of the bare glassy carbon electrode. Controlled potential electrolysis experiments verify the production of ammonia, hydrazine and hydroxylamine, showing the electrocatalytic character and the stability of this modified electrode. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Original languageEnglish
Pages93-100
Number of pages8
DOIs
Publication statusPublished - 1 Jun 2011
Externally publishedYes
Eventconference -
Duration: 1 Jun 2011 → …

Conference

Conferenceconference
Period1/06/11 → …

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  • Cite this

    Calfumán, K., Dreyse, P., García, C., Aguirre, M. J., Beltrán, T., Guillamón, E., Sorribes, I., Vicent, C., Llusar, R., & Isaacs, M. (2011). Macromolecular Symposia. 93-100. Paper presented at conference, . https://doi.org/10.1002/masy.201150613